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Wednesday, August 14, 2013

Synthesizing Cyclohexene by Dehydrating Cyclohexanol

Synthesizing Cyclohexene by Dehydrating Cyclohexanol Abstract 12.0mL of 85% phosphorous acid, 10.0mL of cyclohexanol and heat were used to baffle an alcohol dehydration response and produce 5.85g of cyclohexene. The percent potency was found to be 74.84% later being washed with 10% sodium carbonate and dry out with anhydrous Na2SO4. IR was used, on with a bromine runnel to confirm the identity of the impudently formed cyclohexene. Introduction In entire chemistry, many different artificer concourses exist that have tendencies to move with each other in specific ways. Four principal(prenominal) types of replys relevant to this experiment atomic number 18 uni/di-molecular nucleophilic replacing (SN1 and SN2) and uni/di-molecular elimination (E1 and E2). In roughly cases, SN1 a good turn competes with E1, and SN2 oftentimes competes with E2 reactions. In a SN2 reaction, a nucleophile comes in opposition with a substratum geek and works to replace a sledding group on the subst stride. A nucleophile is a atom that is wee-wee to donate an negatron pair to a substratum (electrophile). When approach shot the electrophile, the nucleophile comes from the blow side of the going group (backside attack).
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As the nucleophile attaches, the go out group simultaneously departs (concerted rxn), deviation a new blood cell with an inverted stereocenter configuration from the original. inviolable loss groups be those that ar most easily replaced by the nucleophile, usually being antiquated bases and small in sizing (halogens). The weaker the base, the less inclined the leaving group is to stick with the substrate and more likely it is to transmit when a stronger nucleophile is introduced. Since SN2 reactions are concerted, the rate of the reaction can be directly related to the concentrations of the substrate and nucleophile (Rate = k[sub][nuc]) in solution. Example SN2 reaction: As mentioned earlier, E2 elimination reactions often compete with SN2 mainly depending on the basicity and hindrance of the nucleophile. However, the...If you want to determine a full essay, assign up it on our website: Ordercustompaper.com

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